In Pokemon Masters players can collect Trainers along with Pokemon to build up a dream team of 3 trainers. A player takes 3 trainers along with him to Pokemon Masters League in Pasio.
Each trainer has a specific Pokemon know as Sync Pair, with which they can work and activate Sync Moves.
A special Syna Outfits can be used to change a trainers Sync Pair Pokemon.
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Trainers List
| Trainer | Base Potential | Pokemon |
|---|---|---|
| Olivia | 5 Star | Olivia and Lycanroc (Midnight Form) |
| Phoebe | 5 Star | Phoebe and Dusclops |
| Cheren | 5 Star | Cheren and Stoutland |
| Blue | 5 Star | Blue and Pidgeot |
| Acerola | 5 Star | Acerola and Palossand |
| Lyra | 5 Star | Lyra and Chikorita Lyra and Bayleef Lyra and Meganium |
| Rosa | 5 Star | Rosa and Servine Rosa and Snivy Rosa and Serperior |
| Karen | 5 Star | Karen and Houndoom Karen and Mega Houndoom |
| Brendan | 5 Star | Brendan and Treecko |
| Hilbert | 5 Star | Hilbert and Oshawatt |
| Kris | 5 Star | Kris and Feraligatr Kris and Croconaw Kris and Totodile |
| Viola | 4 Star | Viola and Surskit Viola and Masquerain |
| Blaine | 4 Star | Blaine and Ponyta |
| Bruno | 4 Star | Bruno and Machamp |
| Agatha | 4 Star | Agatha and Mega Gengar Agatha and Gengar |
| Sophocles | 4 Star | Sophocles and Togedemaru |
| Wikstrom | 4 Star | Wikstrom and Aegislash (Shield Forme) Wikstrom and Aegislash (Blade Forme) |
| Will | 4 Star | Will and Xatu |
| Grant | 4 Star | Grant and Amaura |
| Roxie | 4 Star | Roxie and Whirlipede |
| Lorelei | 4 Star | Lorelei and Lapras |
| Marshal | 4 Star | Marshal and Conkeldurr |
| Clair | 4 Star | Clair and Kingdra |
| Siebold | 4 Star | Siebold and Clawitzer |
| Noland | 4 Star | Noland and Mega Pinsir Noland and Pinsir |
| Flint | 4 Star | Flint and Infernape |
| Shauntal | 4 Star | Shauntal and Chandelure |
| Nanu | 4 Star | Nanu and Persian |
| Drake | 4 Star | Drake and Salamence |
| Whitney | 4 Star | Whitney and Miltank |
| Koga | 4 Star | Koga and Crobat |
| Gardenia | 4 Star | Gardenia and Roserade |
| Thorton | 4 Star | Thorton and Bronzong |
| Kahili | 4 Star | Kahili and Toucannon |
| Hau | 4 Star | Hau and Raichu (Alola Form) |
| Flannery | 3 Star | Flannery and Torkoal |
| Crasher Wake | 3 Star | Crasher Wake and Floatzel |
| Wulfric | 3 Star | Wulfric and Avalugg |
| Janine | 3 Star | Janine and Ariados |
| Sygna Suit Brock | 3 Star | Sygna Suit Brock and Tyranitar |
| Liza | 3 Star | Liza and Lunatone |
| Skyla | 3 Star | Skyla and Swanna |
| Brycen | 3 Star | Brycen and Cryogonal |
| Winona | 3 Star | Winona and Pelipper |
| Marley | 3 Star | Marley and Arcanine |
| Korrina | 3 Star | Korrina and Lucario Korrina and Mega Lucario |
| Tate | 3 Star | Tate and Solrock |
| Roark | 3 Star | Roark and Cranidos |
| Clay | 3 Star | Clay and Palpitoad |
| Brock | 3 Star | Brock and Onix |
| Candice | 3 Star | Candice and Abomasnow |
| Ramos | 3 Star | Ramos and Weepinbell |
| Roxanne | 3 Star | Roxanne and Nosepass |
| Lt. Surge | 3 Star | Lt. Surge and Voltorb |
| Hapu | 3 Star | Hapu and Mudsdale |
| Erika | 3 Star | Erika and Vileplume |
| Marlon | 3 Star | Marlon and Carracosta |
| Pryce | 3 Star | Pryce and Dewgong Pryce and Seel |
| Barry | 3 Star | Barry and Piplup Barry and Prinplup Barry and Empoleon |
| Iris | 3 Star | Iris and Haxorus |
| Bugsy | 3 Star | Bugsy and Mega Beedrill Bugsy and Beedrill |
| Maylene | 3 Star | Maylene and Meditite |
| Main Character | 3 Star | Player and Pikachu |
| Mina | 3 Star | Mina and Granbull |
| Cheryl | 3 Star | Cheryl and Blissey |
| Brawly | 3 Star | Brawly and Makuhita |
| Misty | 3 Star | Misty and Starmie |
| Norman | 3 Star | Norman and Slaking |
